Effect Of Mordant On The Color-Fastness of Natural Dye


  
PURPOSE


The purpose of this experiment was to determine the effect of various amounts of mordant on the color-fastness of natural dye. 

I became interested in this idea when I realized while looking at Native American baskets in a museum that they had held their color for hundreds of years.

 I began to wonder how this was possible without the benefit of modern technology.  The information gained from this experiment could benefit people who are still using natural dyes today.




HYPOTHESIS

 My hypothesis was that increasing the amount of mordant would increase the color-fastness of the natural dye. 

  I based my hypothesis on statement in the book Materials Science: Dyes, Paints, and Adhesives By Brian Kemp. It stated that the more mordant used the better the dyestuffs hold fast to the fabric.

EXPERIMENT DESIGN

      The constants in this study were:
  •  The kind of dye
  •  The kind of mordant
  •  The amount of time that the cloth samples were in the dye solution
  •  The temperature of the dye mixture (boiling)
  •  The type of cloth (cotton).
  •  The washer used to wash the cloth samples.
  •  The detergent used in the washing process.
  •  The colorimeter
  • The container in which the dye is boiled and the samples of cloth are dyed
  •  The temperature the cloth is air dried after dying

The manipulated variable was the amount of mordant used during the staining process. 

The responding variable was the lightness of the dyed cloth after repeated washing.  

To measure the responding variable I used a Hunter reflectance colorimeter to determine the lightness of the dyed cloth samples.  

  
MATERIALS
              

QUANTITY
ITEM DESCRIPTION
60
Samples of 100% cotton cloth squares
2  
Bags of natural dye
1  
Colorimeter
1  
Box of potassium aluminum sulfate
1  
Washer
1
Detergent
2  
Pots
1
Timer
1
Measuring cup
1
Clothes pins
14
Clothesline
1
Stove

           



PROCEDURES

1. Prepare 1 3/4 yards of cloth by washing and drying with no fabric softener

2. Cut the cloth into 5x5 pieces (62 needed)

3. Divide the sixty-two pieces of cloth into five groups of ten and five groups of two.

4. Label each piece of cloth in the left hand corner with a permanent marker.  Each group of ten should have a different label. Stating “M” for mordant, then the amount of mordant, a dash and the cloth number in the group.

5. Store each group of cloth in a separate baggies.

6. Prepare the natural dye by opening four cans of beets.

A.) Pour the beets into a pot through a strainer

B.) Use your hands to squeeze the beets to get the remaining dye out

C.) Pour 3 cans of water over the top of the beets so that the dye that you couldn’t get out will drain into the pot.

D.) Strain the dye three times(or more if needed) to make sure that the beet pulp does not get mixed in with the solution.

E.) Bring the dye to a boil and let it boil for 1 minute.

F.) Separate the dye equally into five glass bowls. 

7. Dye the cloth 

A.) Add x amount of mordant (0, 2, 10, 25, or 50) in a pot with  a bowl of the natural dye solution.

B.) Using a timer once solution starts to boil time for 5 minutes

C.) Put one group of ten cloth squares into the solution all at the same time (this group should be marked appropriately for the amount of mordant that is in the solution.)

D.) Set the timer for 20 minutes. Once all the cloth samples have been dropped in the solution start the timer. 

E.) When timer hits zero remove cloth samples from solution using tongs.

8. Cool and dry on a clothesline for 24 hours then remove and store. Placing each group in separate baggies.

9.  Repeat steps 8-9 five times until you have used the amount of mordant in each group (0, 2, 10, 25, 50)

10. Wash the dyed cloth samples separately the first time in their groups of ten and dry in the same manner.

11.  Look at the cloth samples and see if there is a visible difference in the coloration. If there isn’t then wash the cloth samples again and again until there is a visible difference in the coloration.

12. Once again dry and store in baggies
13. Use the hunter colorimeter at Tree Top to measure the darkness of the dye that is remaining in the cloth.

A.) Turn on the computer and colorimeter

B.) Show the colorimeter what white is by placing the white tile over the hole on the top of the colorimeter. Press F3 to make the colorimeter read the tile.

C.) Repeat step 13b. with the black tile.

D.) Take your already dyed and washed cloth samples and place them one at a time over the top of the hole.  Place the black cylinder on top of the cloth over the hole.

E.) Press F3 so the colorimeter will read the cloth sample.

F.) Look at the label on the cloth 

G.) Copy it down into the column on the computer that says ID and press enter to save the data onto the table

H.) Repeat step 13d. through 13g. until all your cloth samples have been read by the colorimeter.

14. Print the data and turn off the colorimeter and the computer.

14. Average your results from the colorimeter for each group of ten and record them on a table.

 

RESULTS

The original purpose of this experiment was to determine the effect of various amounts of mordant on the color-fastness of natural dye. 

The results of this experiment were the whiteness (luminance) values given by the colorimeter.  For the control group with 0 grams of mordant, the average whiteness was 78.60.  Using 2 grams of mordant, the whiteness was 76.96.  For the 10 grams of mordant group the whiteness was 77.52  for the 25 grams of mordant group, the whiteness was 77.08.  Finally the 50 grams of mordant group had a reading of 77.24. These results show that the amount of mordant used in the dyeing process does not make a big difference. However some amount of mordant is better than none.

 CONCLUSION


My hypothesis was that increasing the amount of mordant would increase the color-fastness of the natural dye. 

The results indicate that this hypothesis should be rejected. It is true that adding mordant increases colorfastness, but it is not true that multiplying the amount of mordant helps. 

Because of the results of this experiment, I wonder if different types of mordant would make a larger impact on the colorfastness of the fabric rather than different amounts. It is also possible that beet juice was no the ideal dye  so it would be desirable to redo this experiment using a powerful dye.

 If I were to conduct this project I would use a different type of dye, cloth, and or mordant.

Researched by - Audre H.


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